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Highly Stereoselective C—C Bond Formation by Rhodium-Catalyzed Tandem Ylide Formation/[2,3]-Sigmatropic Rearrangement Between Donor/Acceptor Carbenoids and Chiral Allylic Alcohols
The tandem ylide-formation/[2,3]-sigmatropic rearrangement between donor/acceptor rhodium-carbenoids and chiral allyl alcohols is a convergent C—C bond forming process, which generates two vicinal stereogenic centers. Any of the four possible stereoisomers can be selectively synthesized by appropria...
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| Hlavní autoři: | , , |
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| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
2012
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3413634/ https://ncbi.nlm.nih.gov/pubmed/22694052 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja303023n |
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