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Highly Stereoselective C—C Bond Formation by Rhodium-Catalyzed Tandem Ylide Formation/[2,3]-Sigmatropic Rearrangement Between Donor/Acceptor Carbenoids and Chiral Allylic Alcohols

The tandem ylide-formation/[2,3]-sigmatropic rearrangement between donor/acceptor rhodium-carbenoids and chiral allyl alcohols is a convergent C—C bond forming process, which generates two vicinal stereogenic centers. Any of the four possible stereoisomers can be selectively synthesized by appropria...

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Autori principali: Li, Zhanjie, Parr, Brendan T., Davies, Huw M. L.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2012
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3413634/
https://ncbi.nlm.nih.gov/pubmed/22694052
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja303023n
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