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Diastereoselective Chelation-Controlled Additions to β-Silyloxy Aldehydes
[Image: see text] A general diastereoselective method for the addition of dialkylzincs and (E)-di and (E)-trisubstituted vinylzinc reagents to β-silyloxy aldehydes is presented. This method employs alkyl zinc triflate and nonaflate Lewis acids and affords chelation-controlled products (6:1 to > 2...
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| Hauptverfasser: | , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2012
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3401491/ https://ncbi.nlm.nih.gov/pubmed/22721430 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol301354w |
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