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A Solvatochromic Model Calibrates Nitriles’ Vibrational Frequencies to Electrostatic Fields

Electrostatic interactions provide a primary connection between a protein’s three-dimensional structure and its function. Infrared (IR) probes are useful because vibrational frequencies of certain chemical groups, such as nitriles, are linearly sensitive to local electrostatic field, and can serve a...

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Bibliografische gegevens
Hoofdauteurs: Bagchi, Sayan, Fried, Stephen D., Boxer, Steven G.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2012
Onderwerpen:
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3384762/
https://ncbi.nlm.nih.gov/pubmed/22694663
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja303895k
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