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Solvent-induced infrared frequency shifts in aromatic nitriles are quantitatively described by the vibrational Stark effect
The physical properties of solvents strongly affect the spectra of dissolved solutes, and this phenomenon can be exploited to gain insight into the solvent-solute interaction. The large solvatochromic shifts observed for many dye molecules in polar solvents are due to variations in the solvent react...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3404211/ https://ncbi.nlm.nih.gov/pubmed/22448878 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp301054e |
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