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Nitrile Bonds as Infrared Probes of Electrostatics in Ribonuclease S
Three different nitrile-containing amino acids, para-cyanophenylalanine, meta-cyanophenylalanine and S-cyano homocysteine, have been introduced near the active site of the semi-synthetic enzyme Ribonuclease S (RNase S) to serve as probes of electrostatic fields. Vibrational Stark spectra, measured d...
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2010
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2959148/ https://ncbi.nlm.nih.gov/pubmed/20883003 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp106406p |
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