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Nitrile Bonds as Infrared Probes of Electrostatics in Ribonuclease S

Three different nitrile-containing amino acids, para-cyanophenylalanine, meta-cyanophenylalanine and S-cyano homocysteine, have been introduced near the active site of the semi-synthetic enzyme Ribonuclease S (RNase S) to serve as probes of electrostatic fields. Vibrational Stark spectra, measured d...

Täydet tiedot

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Bibliografiset tiedot
Päätekijät: Fafarman, Aaron, Boxer, Steven G.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: 2010
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC2959148/
https://ncbi.nlm.nih.gov/pubmed/20883003
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jp106406p
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