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9-Mercaptodethiobiotin is Formed as a Competent Catalytic Intermediate by Escherichia coli Biotin Synthase
Biotin synthase (BS) catalyzes the oxidative addition of a sulfur atom to dethiobiotin (DTB) to generate the biotin thiophane ring. This enzyme is an S-adenosylmethionine (AdoMet) radical enzyme that catalyzes the reductive cleavage of AdoMet, generating methionine and a transient 5´-deoxyadenosyl r...
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| Auteurs principaux: | , , |
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| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2008
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3380106/ https://ncbi.nlm.nih.gov/pubmed/18690713 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi801035b |
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