Enantioselective Decarboxylative Alkylation Reactions: Catalyst Development, Substrate Scope, and Mechanistic Studies

α-Quaternary ketones are accessed through novel enantioselective alkylations of allyl and propargyl electrophiles by unstabilized prochiral enolate nucleophiles in the presence of palladium complexes with various phosphinooxazoline (PHOX) ligands. Excellent yields and high enantiomeric excesses are...

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Detaylı Bibliyografya
Asıl Yazarlar: Behenna, Douglas C., Mohr, Justin T., Sherden, Nathaniel H., Marinescu, Smaranda C., Harned, Andrew M., Tani, Kousuke, Seto, Masaki, Ma, Sandy, Novák, Zoltán, Krout, Michael R., McFadden, Ryan M., Roizen, Jennifer L., Enquist, John A., White, David E., Levine, Samantha R., Petrova, Krastina V., Iwashita, Akihiko, Virgil, Scott C., Stoltz, Brian M.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: 2011
Konular:
Article
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC3365686/
https://ncbi.nlm.nih.gov/pubmed/22083969
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201003383
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