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Unusual Allylpalladium Carboxylate Complexes: Identification of the Resting State of Catalytic Enantioselective Decarboxylative Ketone Allylic Alkylation Reactions
Palladium poprocks: Hold on to your CO(2)! Enantioselective Pd-catalyzed decarboxylative alkylation of ketone enolates proceeds via η(1)-σ-allyl Pd-carboxylate complexes by slow loss of CO(2).
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| Main Authors: | , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2009
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2880474/ https://ncbi.nlm.nih.gov/pubmed/19672907 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.200902575 |
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