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Unusual Allylpalladium Carboxylate Complexes: Identification of the Resting State of Catalytic Enantioselective Decarboxylative Ketone Allylic Alkylation Reactions

Palladium poprocks: Hold on to your CO(2)! Enantioselective Pd-catalyzed decarboxylative alkylation of ketone enolates proceeds via η(1)-σ-allyl Pd-carboxylate complexes by slow loss of CO(2).

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Autors principals: Sherden, Nathaniel H., Behenna, Douglas C., Virgil, Scott C., Stoltz, Brian M.
Format: Artigo
Idioma:Inglês
Publicat: 2009
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2880474/
https://ncbi.nlm.nih.gov/pubmed/19672907
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.200902575
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