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Synthesis of Silyloxy Dienes by Silylene Tranfer to Divinyl Ketones: Application to the Asymmetric Sythesis of Substituted Cyclohexanes

Silver-catalyzed silylene transfer to divinyl ketones provided 2-silyloxy-1,3-dienes with control of stereochemistry and regioselectivity. The products participated in Diels–Alder reactions with electron-deficient alkenes and imines to form six-membered ring products diastereoselectively. Cycloaddit...

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Autors principals: Ventocilla, Christian C., Woerpel, K. A.
Format: Artigo
Idioma:Inglês
Publicat: 2012
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3336154/
https://ncbi.nlm.nih.gov/pubmed/22372733
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo202650k
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