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New Directing Groups for Metal-Catalyzed Asymmetric Carbon–Carbon Bond-Forming Processes: Stereoconvergent Alkyl–Alkyl Suzuki Cross-Couplings of Unactivated Electrophiles

The ability of two common protected forms of amines (carbamates and sulfonamides) to serve as directing groups in nickel-catalyzed Suzuki reactions has been exploited in the development of catalytic asymmetric methods for cross-coupling unactivated alkyl electrophiles. Racemic secondary bromides and...

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Bibliografische gegevens
Hoofdauteurs: Wilsily, Ashraf, Tramutola, Francesco, Owston, Nathan A., Fu, Gregory C.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2012
Onderwerpen:
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3333791/
https://ncbi.nlm.nih.gov/pubmed/22443409
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja301612y
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