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Photoinduced, Copper-Catalyzed Carbon–Carbon Bond Formation with Alkyl Electrophiles: Cyanation of Unactivated Secondary Alkyl Chlorides at Room Temperature

We have recently reported that, in the presence of light and a copper catalyst, nitrogen nucleophiles such as carbazoles and primary amides undergo C–N coupling with alkyl halides under mild conditions. In the present study, we establish that photoinduced, copper-catalyzed alkylation can also be app...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Ratani, Tanvi S., Bachman, Shoshana, Fu, Gregory C., Peters, Jonas C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4666296/
https://ncbi.nlm.nih.gov/pubmed/26491957
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b08452
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