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Identification of the product of Toxoflavin lyase: degradation via a Baeyer-Villiger oxidation
Toxoflavin (an azapteridine) is degraded to a single product by toxoflavin lyase (TflA) in a reaction dependent on reductant, Mn(II), and oxygen. The isolated product was fully characterized by NMR and MS and was identified as a triazine in which the pyrimidine ring was oxidatively degraded. A mecha...
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| Autors principals: | , , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2012
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3332044/ https://ncbi.nlm.nih.gov/pubmed/22304755 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja211759n |
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