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A Nonenzymatic Acid/Peracid Catalytic Cycle for the Baeyer-Villiger Oxidation
[Image: see text] The combined action of carbodiimide and hydrogen peroxide upon exposure to carboxylic acid catalysts serves to generate transient peracids that can be engaged in the Baeyer-Villiger rearrangement of ketones to lactones. Up to 35 turnovers of the catalytic cycle may be achieved. The...
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| Main Authors: | , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2008
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4125978/ https://ncbi.nlm.nih.gov/pubmed/18553911 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol8010248 |
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