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Baeyer-Villiger Rearrangement of a Substituted Pyrrole by Oxone
Pyrroloxyls have been reported to exhibit very narrow EPR spectral lines, essential for in vivo imaging. En route to pyrroloxyls, we observed an unexpected Baeyer-Villiger rearrangement, leading to loss of aromaticity and formation of a 4,5-dihydro-1H-ketopyrrole.
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2014
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4041875/ https://ncbi.nlm.nih.gov/pubmed/24910476 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2014.04.004 |
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