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Competitive [2,3]- and [1,2]-Oxonium Ylide Rearrangements. Concerted or Stepwise?
The axial-equatorial conformational isomer distribution of the reactant diazoacetoacetate or its metal carbene intermediate is reflected in Rh(II) catalyzed oxonium ylide forming reactions of 3-(trans-2-arylvinyl)tetrahydropyranone- 5-diazoacetoacetates that afford diastereoisomeric products for bot...
में बचाया:
| मुख्य लेखकों: | , , , , |
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| स्वरूप: | Artigo |
| भाषा: | Inglês |
| प्रकाशित: |
2012
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| विषय: | |
| ऑनलाइन पहुंच: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3321102/ https://ncbi.nlm.nih.gov/pubmed/22409577 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol300213u |
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