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Spectroscopic and computational characterization of Cu(II)–OOR (R = H or cumyl) complexes bearing a Me(6)-tren ligand()
A copper(II)–hydroperoxo complex, [Cu(Me(6)-tren)(OOH)](+) (2), and a copper(II)–cumylperoxo complex, [Cu(Me(6)-tren)(OOC(CH(3))(2)Ph)](+) (3), were synthesized by reacting [Cu(Me(6)-tren)(CH(3)CN)](2+) (1) with H(2)O(2) and cumyl-OOH, respectively, in the presence of triethylamine. These intermedia...
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| Main Authors: | , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3318924/ https://ncbi.nlm.nih.gov/pubmed/21258722 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c0dt01036g |
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