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Iron(III)/NaBH(4)-Mediated Additions to Unactivated Alkenes: Synthesis of Novel 20′-Vinblastine Analogues

[Image: see text] An Fe(III)/NaBH(4)-mediated reaction for the functionalization of unactivated alkenes is described defining the alkene substrate scope, establishing the exclusive Markovnikov addition, exploring a range of free radical traps, examining the Fe(III) salt and initiating hydride source...

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Main Authors: Leggans, Erick K., Barker, Timothy J., Duncan, Katharine K., Boger, Dale L.
Formato: Artigo
Idioma:Inglês
Publicado: 2012
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3306530/
https://ncbi.nlm.nih.gov/pubmed/22369097
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol300173v
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