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Fe(III)/NaBH(4)-Mediated Free Radical Hydrofluorination of Unactivated Alkenes

A powerful Fe(III)/NaBH(4)-mediated free radical hydrofluorination of unactivated alkenes is disclosed using Selectfluor as a source of fluorine and resulting in exclusive Markovnikov addition. In contrast to the traditional and unmanageable free radical hydrofluorination of alkenes, the Fe(III)/NaB...

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Detalhes bibliográficos
Main Authors: Barker, Timothy J., Boger, Dale L.
Formato: Artigo
Idioma:Inglês
Publicado em: 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3425717/
https://ncbi.nlm.nih.gov/pubmed/22860624
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja3063716
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