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Lifetimes and Reaction Pathways of Guanine Radical Cations and Neutral Guanine Radicals in an Oligonucleotide in Aqueous Solutions
The exposure of guanine in the oligonucleotide 5’-d(TCGCT) to one-electron oxidants leads initially to the formation of the guanine radical cation G(•+), its deptotonation product G(−H)(•) and, ultimately, to various two- and four-electron oxidation products via pathways that depend on the oxidants...
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| Autori principali: | , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2012
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3303975/ https://ncbi.nlm.nih.gov/pubmed/22329445 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja212186w |
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