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Measurement and Theory of Hydrogen Bonding Contribution to Isosteric DNA Base Pairs

We address the recent debate surrounding the ability of 2,4-difluorotoluene (F), a low-polarity mimic of thymine (T), to form a hydrogen-bonded complex with adenine in DNA. The hydrogen bonding ability of F has been characterized as small to zero in various experimental studies, and moderate to smal...

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Main Authors: Khakshoor, Omid, Wheeler, Steven E., Houk, K. N., Kool, Eric T.
Format: Artigo
Jezik:Inglês
Izdano: 2012
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC3293652/
https://ncbi.nlm.nih.gov/pubmed/22300089
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja210475a
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