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Complications from Dual Roles of Sodium Hydride as a Base and as a Reducing Agent

[Image: see text] Sodium hydride is a common reagent for substrate activation in nucleophilic substitution reactions. Sodium hydride can behave both as a base and as a source of hydride. This dual ability in the presence of an electrophile such as benzyl bromide results in the formation of byproduct...

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Bibliographic Details
Main Authors: Hesek, Dusan, Lee, Mijoon, Noll, Bruce C., Fisher, Jed F., Mobashery, Shahriar
Format: Artigo
Language:Inglês
Published: 2009
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC3286627/
https://ncbi.nlm.nih.gov/pubmed/19215116
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo802706d
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