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Synthesis and shift-reagent-assisted full NMR assignment of the bacterial (Z(8), E(2), ω)-undecaprenol
The repeating isoprene unit is a fundamental biosynthetic motif. Repetitive structure presents challenges both for synthesis and for structural characterization. In this synthesis of the (Z(8), E(2), ω)-undecaprenol of prokaryotic glycobiology, we exemplify solutions to these challenges. Allylation...
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| Published in: | Chem Commun (Camb) |
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| Main Authors: | , , , , |
| Format: | Artigo |
| Language: | Inglês |
| Published: |
2017
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5749266/ https://ncbi.nlm.nih.gov/pubmed/29139490 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7cc06781j |
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