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Preparation of aluminum(III) (bis(amido)pyridine)(thiolate) complexes: unexpected transmetalation mediated by LiAlH(4)
Treatment of an unsymmetrical bis(imino)pyridyl-thiolate zinc(II) complex [Zn(II)(LN(3)S)(OTf)] (1) with LiAlH(4) results in the double reduction of the two imino groups in the ligand backbone, and at the same time causes a rare transmetalation reaction to occur. The products formed in this reaction...
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| 主要な著者: | , , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2012
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3278085/ https://ncbi.nlm.nih.gov/pubmed/22345823 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.ica.2011.09.056 |
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