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Preparation of aluminum(III) (bis(amido)pyridine)(thiolate) complexes: unexpected transmetalation mediated by LiAlH(4)

Treatment of an unsymmetrical bis(imino)pyridyl-thiolate zinc(II) complex [Zn(II)(LN(3)S)(OTf)] (1) with LiAlH(4) results in the double reduction of the two imino groups in the ligand backbone, and at the same time causes a rare transmetalation reaction to occur. The products formed in this reaction...

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Autori principali: Badiei, Yosra M., Jiang, Yunbo, Widger, Leland R., Siegler, Maxime A., Goldberg, David P.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2012
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3278085/
https://ncbi.nlm.nih.gov/pubmed/22345823
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.ica.2011.09.056
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