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Insights into the Mechanistic Dichotomy of the Protein Farne-syltransferase Peptide Substrates CVIM and CVLS
Protein farnesyltransferase (FTase) catalyzes farnesylation of a variety of peptide substrates. (3)H α-secondary kinetic isotope effect measurements of two peptide substrates, CVIM and CVLS, are significantly different and have been proposed to reflect a rate-limiting S(N)2-like transition state wit...
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| Autors principals: | , , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2012
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3277741/ https://ncbi.nlm.nih.gov/pubmed/22206225 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja209650h |
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