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Characterization of an O(2) Adduct of an Active Cobalt-Substituted Extradiol-Cleaving Catechol Dioxygenase
The first example for an O(2) adduct of an active Co-substituted oxygenase is observed in the extradiol ring cleavage of the electron-poor substrate 4-nitrocatechol (4NC) by Co(II)-homoprotocatechuate 2,3-dioxygenase (Co-HPCD). Upon O(2) binding to the high-spin Co(II) (S = 3/2) enzyme-substrate com...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3262093/ https://ncbi.nlm.nih.gov/pubmed/22175783 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2095365 |
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