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Three-Component Coupling Sequence for the Regiospecific Synthesis of Substituted Pyridines
A de novo synthesis of substituted pyridines is described that proceeds through nucleophilic addition of a dithiane anion to an α,β-unsaturated carbonyl followed by metallacycle-mediated union of the resulting allylic alcohol with preformed TMS-imines (generated in situ by the low temperature reacti...
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| Autors principals: | , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2011
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3262091/ https://ncbi.nlm.nih.gov/pubmed/22103772 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2105703 |
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