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Synthesis of Catechols from Phenols via Pd-Catalyzed Silanol-Directed C–H Oxygenation
A silanol-directed, Pd-catalyzed C–H oxygenation of phenols into catechols is presented. This method is highly site selective and general, as it allows for oxygenation of not only electron-neutral- but also electron poor phenols. This method operates via a silanol-directed acetoxylation, followed by...
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| Autori principali: | , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2011
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3250381/ https://ncbi.nlm.nih.gov/pubmed/21999512 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja208572v |
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