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Synthesis of Catechols from Phenols via Pd-Catalyzed Silanol-Directed C–H Oxygenation

A silanol-directed, Pd-catalyzed C–H oxygenation of phenols into catechols is presented. This method is highly site selective and general, as it allows for oxygenation of not only electron-neutral- but also electron poor phenols. This method operates via a silanol-directed acetoxylation, followed by...

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保存先:
書誌詳細
主要な著者: Huang, Chunhui, Ghavtadze, Nugzar, Chattopadhyay, Buddhadeb, Gevorgyan, Vladimir
フォーマット: Artigo
言語:Inglês
出版事項: 2011
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC3250381/
https://ncbi.nlm.nih.gov/pubmed/21999512
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja208572v
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