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Silanol - a Traceless Directing Group for Pd-Catalyzed o-Alkenylation of Phenols

A silanol-directed, Pd(II)-catalyzed C–H alkenylation of phenols is reported. This work features silanol, as a novel traceless directing group, and a directed o-C-H alkenylation of phenols. This new method allows for efficient synthesis of diverse alkenylated phenols, including an estrone derivative...

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Detalhes bibliográficos
Main Authors: Huang, Chunhui, Chattopadhyay, Buddhadeb, Gevorgyan, Vladimir
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3156791/
https://ncbi.nlm.nih.gov/pubmed/21766826
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja204924j
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