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TBDPS and Br-TBDPS Protecting Groups as Efficient Aryl Group Donors in Pd-Catalyzed Arylation of Phenols and Anilines
It was shown that the TBDPS protecting group can serve as an efficient phenyl group donor for o-bromophenols via the Pd-catalyzed C—H arylation, followed by a routine TBAF deprotection of the forming silacycles. Employment of the newly designed Br-TBDPS protecting group in the same sequence allows f...
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| Main Authors: | , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2009
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2739120/ https://ncbi.nlm.nih.gov/pubmed/19722665 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja904791y |
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