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TBDPS and Br-TBDPS Protecting Groups as Efficient Aryl Group Donors in Pd-Catalyzed Arylation of Phenols and Anilines

It was shown that the TBDPS protecting group can serve as an efficient phenyl group donor for o-bromophenols via the Pd-catalyzed C—H arylation, followed by a routine TBAF deprotection of the forming silacycles. Employment of the newly designed Br-TBDPS protecting group in the same sequence allows f...

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Bibliographic Details
Main Authors: Huang, Chunhui, Gevorgyan, Vladimir
Format: Artigo
Language:Inglês
Published: 2009
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2739120/
https://ncbi.nlm.nih.gov/pubmed/19722665
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja904791y
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