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Synthesis of the C21–C34 fragment of antascomicin B
The C21–C34 fragment of the potent FKBP12-binding macrolide antascomicin B was prepared using Ireland-Claisen and allylic diazene rearrangements to establish the C26/C27 and the C23 stereocenters, respectively. Directed hydrogenation installed the C29 β-configuration. The fragment possesses 7 of the...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3244276/ https://ncbi.nlm.nih.gov/pubmed/22199407 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2011.09.027 |
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