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Revisitation of the βCl-Elimination Reaction of d-Amino Acid Oxidase: NEW INTERPRETATION OF THE REACTION THAT SPARKED FLAVOPROTEIN DEHYDROGENATION MECHANISMS
d-Amino acid oxidase (DAAO) from pig has been reported to catalyze the β-elimination of Cl(−) from βCl-d-alanine via abstraction of the substrate α-H as H(+) (“carbanion mechanism”) (Walsh, C. T., Schonbrunn, A., and Abeles, R. H. (1971) J. Biol. Chem. 246, 6855–6866). In view of the fundamental mec...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Society for Biochemistry and Molecular Biology
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3220486/ https://ncbi.nlm.nih.gov/pubmed/21949129 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1074/jbc.M111.266536 |
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