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Rate-Limiting Steps and Role of Active Site Lys443 in the Mechanism of Carbapenam Synthetase
Carbapenam synthetase (hereafter named CPS) catalyzes the formation of the β-lactam ring in the biosynthetic pathway to (5R)-carbapen-2-em-3-carboxylate, the simplest of the carbapenem antibiotics. Kinetic studies showed remarkable tolerance to substrate stereochemistry on the turnover rate, but did...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3198785/ https://ncbi.nlm.nih.gov/pubmed/17658887 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi0618464 |
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