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A Simple Method for the Determination of Enantiomeric Excess and Identity of Chiral Carboxylic Acids

The association between an achiral copper(II) host (1) and chiral carboxylate guests was studied using exciton-coupled circular dichroism (ECCD). Enantiomeric complexes were created upon binding of the enantiomers of the carboxylate guests to the host, and the sign of the resultant CD signal allowed...

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Hlavní autoři: Joyce, Leo A., Maynor, Marc S., Dragna, Justin M., da Cruz, Gabriella M., Lynch, Vincent M., Canary, James W., Anslyn, Eric V.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2011
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3179184/
https://ncbi.nlm.nih.gov/pubmed/21780788
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja205775g
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