Rapid Identification, Enantiomeric Excess and Concentration Determination Using Simple Racemic Metal Complexes

[Image: see text] Racemic-metal complexes were used to determine identity, enantiomeric excess (ee) and concentration of chiral diamines using MLCT bands in circular dichroism spectroscopy. It takes under just two minutes per sample to determine [G](t) and %R with tolerable errors (19% and 4% respec...

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Bibliographic Details
Main Authors: Nieto, Sonia, Lynch, Vincent M., Anslyn, Eric V., Kim, Hyunwoo, Chin, Jik
Format: Artigo
Language:Inglês
Published: 2008
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2749327/
https://ncbi.nlm.nih.gov/pubmed/18939802
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol802085j
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