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In Vivo Self-Hydroxylation of an Iron-Substituted Manganese-Dependent Extradiol Cleaving Catechol Dioxygenase
The homoprotocatechuate 2,3-dioxygenase from Arthrobacter globiformis (MndD) catalyzes the oxidative ring cleavage reaction of its catechol substrate in an extradiol fashion. While this reactivity is more typically associated with nonheme iron enzymes, MndD exhibits an unusual specificity for mangan...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3177297/ https://ncbi.nlm.nih.gov/pubmed/21279661 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1007/s00775-011-0760-4 |
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