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The glmS ribozyme tunes the catalytically critical pK(a) of its coenzyme glucosamine-6-phosphate

The glmS ribozyme-riboswitch is the first known natural catalytic RNA that employs a small molecule cofactor. Binding of glucosamine-6-phosphate (GlcN6P) uncovers the latent self-cleavage activity of the RNA, which adopts a catalytically competent conformation, which is nonetheless inactive, in the...

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書誌詳細
主要な著者: Gong, Bo, Klein, Daniel J., Ferré-D’Amaré, Adrian R., Carey, Paul R.
フォーマット: Artigo
言語:Inglês
出版事項: 2011
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC3174766/
https://ncbi.nlm.nih.gov/pubmed/21848325
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja205185g
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