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Kedarcidin Chromophore–Synthesis of Its Proposed Structure and Evidence for a Stereochemical Revision
A convergent, enantioselective synthesis of the proposed structure of kedarcidin chromophore (1) is described. The route is 24 steps in the longest linear sequence (beginning with the commercial reagent 2,3-O-isopropylidene-d-erythronolactone) with an average yield of 75% per step (overall yield: 0....
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| Main Authors: | , , , |
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| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2007
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3174495/ https://ncbi.nlm.nih.gov/pubmed/17417855 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja071205b |
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