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Enantioselective Total Synthesis of (−)-Citrinadin A and Revision of its Stereochemical Structure

The first enantioselective total synthesis of (−)-citrinadin A has been accomplished in 20 steps from commercially available materials via an approach that minimizes refunctionalization and protection/deprotection operations. The cornerstone of this synthesis features an asymmetric vinylogous Mannic...

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Autors principals: Bian, Zhiguo, Marvin, Christopher C., Martin, Stephen F.
Format: Artigo
Idioma:Inglês
Publicat: 2013
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3748604/
https://ncbi.nlm.nih.gov/pubmed/23837457
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja405547f
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