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Synthesis of Cyclic Enones via Direct Palladium-Catalyzed Aerobic Dehydrogenation of Ketones

α,β-Unsaturated carbonyl compounds are versatile intermediates in the synthesis of pharmaceuticals and biologically active compounds. Here, we report the discovery and application of Pd(DMSO)(2)(TFA)(2) as a catalyst for direct dehydrogenation of cyclohexanones and other cyclic ketones to the corres...

詳細記述

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書誌詳細
主要な著者: Diao, Tianning, Stahl, Shannon S.
フォーマット: Artigo
言語:Inglês
出版事項: 2011
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC3173566/
https://ncbi.nlm.nih.gov/pubmed/21851123
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja206575j
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