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Anti-Markovnikov Hydroalkylation of Allylic Amine Derivatives via a Palladium–Catalyzed Reductive Cross-Coupling Reaction
A palladium-catalyzed hydroalkylation reaction of allylic amine derivatives by alkylzinc reagents is reported. This reductive cross-coupling yields anti-Markovnikov products using a variety of allylic amine protecting groups. Preliminary mechanistic studies suggest that a reversible β-hydride elimin...
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| 主要な著者: | , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2011
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3170748/ https://ncbi.nlm.nih.gov/pubmed/21728336 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja204080s |
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