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Palladium-Catalyzed Allylic Cross-Coupling Reactions of Primary- and Secondary Homoallylic Electrophiles

The Pd(0)-catalyzed allylic cross-coupling of homoallylic tosylate substrates using boronic acids and esters is reported. The reaction uses 2-(4,5-dihydro-2-oxazolyl)quinoline (quinox) as ligand and is performed at ambient temperature. The scope of the reaction is broad in terms of both the boronate...

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Hlavní autoři: Stokes, Benjamin J., Opra, Susanne M., Sigman, Matthew S.
Médium: Artigo
Jazyk:Inglês
Vydáno: 2012
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3412144/
https://ncbi.nlm.nih.gov/pubmed/22742056
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja305403s
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