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Palladium-Catalyzed Enantioselective Intermolecular Coupling of Phenols and Allylic Alcohols

An enantioselective intermolecular coupling of oxygen nucleophiles and allylic alcohols to give β-aryloxycarbonyl compounds is disclosed using a chiral pyridine oxazoline-ligated palladium catalyst under mild conditions. As opposed to the formation of traditional Wacker-type products, enantioselecti...

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Publicat a:J Am Chem Soc
Autors principals: Race, Nicholas J., Schwalm, Cristiane S., Nakamuro, Takayuki, Sigman, Matthew S.
Format: Artigo
Idioma:Inglês
Publicat: 2016
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5180452/
https://ncbi.nlm.nih.gov/pubmed/27960316
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b11486
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