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Enantioselective Acylation of Silyl Ketene Acetals through Fluoride Anion-Binding Catalysis
A highly-enantioselective acylation of silyl ketene acetals with acyl fluorides has been developed to generate useful α, α-disubstituted butyrolactone products. This reaction is promoted by a new thiourea catalyst and 4-pyrrolidinopyridine and represents the first example of enanti-oselective thiour...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3164931/ https://ncbi.nlm.nih.gov/pubmed/21800916 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja205602j |
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