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Pipecolic Acid-Catalyzed Direct Asymmetric Mannich Reactions
[Image: see text] Mannich reactions between aldehydes and N-p-methoxyphenyl-protected α-imino ethyl glyoxylate have been performed using (S)-pipecolic acid as catalyst. The reactions give both syn- and anti-products (dr = 1.4–2:1) with high enantioselectivities (>98% ee). In contrast, (S)-proline...
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| Main Authors: | , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2006
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3164113/ https://ncbi.nlm.nih.gov/pubmed/16494447 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol052861o |
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