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Copper(I)-catalyzed asymmetric decarboxylative Mannich reaction enabled by acidic activation of 2H-azirines

Chiral aziridines are structure units found in many biologically active compounds and are important building blocks in organic synthesis. Herein, by merging nucleophilic generation through copper(I)-catalyzed decarboxylation and activation of poorly electrophilic 2H-azirines through protonation with...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: Zhang, Hai-Jun, Xie, Yan-Cheng, Yin, Liang
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group UK 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6461707/
https://ncbi.nlm.nih.gov/pubmed/30979892
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-019-09750-5
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