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glmS riboswitch binding to the glucosamine-6-phosphate α-anomer shifts the pK(a) toward neutrality
The glmS riboswitch regulates gene expression through a self-cleavage activity. The reaction is catalyzed with the assistance of the metabolite cofactor glucosamine-6-phosphate (GlcN6P), whose amino group is proposed to serve as the general acid during the reaction. This reaction is pH-dependent wit...
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| Main Authors: | , , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2011
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3156831/ https://ncbi.nlm.nih.gov/pubmed/21770472 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi200471c |
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